| Literature DB >> 17638585 |
Chunqi Qian1, Alex Pines, Rachel W Martin.
Abstract
Variable angle spinning (VAS) experiments can be used to measure long-range dipolar couplings and provide structural information about molecules in oriented media. We present a probe design for this type of experiment using a contactless resonator. In this circuit, RF power is transmitted wirelessly via coaxial capacitive coupling where the coupling efficiency is improved by replacing the ordinary sample coil with a double frequency resonator. Our probe constructed out of this design principle has shown favorable properties at variable angle conditions. Moreover, a switched angle spinning correlation experiment is performed to demonstrate the probe's capability to resolve dipolar couplings in strongly aligned molecules.Mesh:
Year: 2007 PMID: 17638585 DOI: 10.1016/j.jmr.2007.06.006
Source DB: PubMed Journal: J Magn Reson ISSN: 1090-7807 Impact factor: 2.229