| Literature DB >> 17602639 |
Yoshiyasu Ichikawa1, Tomonori Yamaoka, Keiji Nakano, Hiyoshizo Kotsuki.
Abstract
Total synthesis of (-)-agelastatin A has been achieved starting from l-arabitol. The highlights in our synthesis include the preparation of vicinal diamine moiety by [3.3] sigmatropic rearrangement of allyl cyanate and construction of central ring-C with ring-closing metathesis.Entities:
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Year: 2007 PMID： 17602639 DOI： 10.1021/ol0709735
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005