| Literature DB >> 17511451 |
Patricia J Melfi1, Sung Kuk Kim, Jeong Tae Lee, Frédéric Bolze, Daniel Seidel, Vincent M Lynch, Jacqueline M Veauthier, Andrew J Gaunt, Mary P Neu, Zhongping Ou, Karl M Kadish, Shunichi Fukuzumi, Kei Ohkubo, Jonathan L Sessler.
Abstract
A uranyl complex, the first metal complex to be formed from the cyclo[n]pyrrole series of expanded porphyrins, is formed when cyclo[6]pyrrole is treated with the uranyl cation under aerobic conditions. Spectroscopic, spectroelectrochemical, and electron spin resonance data of this species are consistent with the ligand in the complex being oxidized to an antiaromatic form.Entities:
Year: 2007 PMID： 17511451 DOI： 10.1021/ic700781t
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165