Literature DB >> 17488121

Highly enantioselective oxidation of sulfides to sulfoxides by a new oxaziridinium salt.

R E del Río1, B Wang, S Achab, L Bohé.   

Abstract

The new oxaziridinium salt 5 (R2 = TBDPS) is an effective reagent for the highly enantioselective oxidation of sulfides to sulfoxides with up to >99% ee and good yields. As such, it represents a new valuable nonmetallic alternative to the existing methods for asymmetric sulfoxidation.

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Year:  2007        PMID: 17488121     DOI: 10.1021/ol0702573

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

1.  2-{[3-Methyl-4-(2,2,2-trifluoro-eth-oxy)pyridin-2-yl]methyl-sulfan-yl}-1H-benzimidazole monohydrate: a monoclinic polymorph.

Authors:  Yu-Feng Chen; Jin-Yao Chen; Ming-Huang Hong; Jie Lu; Guo-Bin Ren
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-06-13

2.  2-{[3-Methyl-4-(2,2,2-trifluoro-eth-oxy)pyridin-2-yl]methyl-sulfan-yl}-1H-benzimidazole monohydrate.

Authors:  Guo-Bin Ren; Ming-Huang Hong; Jia-Liang Zhong; Dong-Xu Yi; Le-Hui Xu
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-01-08

3.  2-{[3-Methyl-4-(2,2,2-trifluoro-eth-oxy)pyridin-2-yl]methyl-sulfan-yl}-1H-benzimidazole propan-2-ol monosolvate: a second monoclinic polymorph.

Authors:  Jin-Ju Ma; Ming-Hui Qi; Ming-Huang Hong; Jie Lu; Guo-Bin Ren
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-06-13

Review 4.  Recent Advances in the Catalytic Asymmetric Reactions of Oxaziridines.

Authors:  Qiao Ren; Wen Yang; Yunfei Lan; Xurong Qin; Youzhou He; Lujiang Yuan
Journal:  Molecules       Date:  2018-10-16       Impact factor: 4.411

  4 in total

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