Literature DB >> 17442749

Agostic interactions in transition metal compounds.

Maurice Brookhart1, Malcolm L H Green, Gerard Parkin.   

Abstract

The impact of agostic interactions (i.e., 3-center-2-electron M-H-C bonds) on the structures and reactivity of organotransition metal compounds is reviewed.

Entities:  

Year:  2007        PMID： 17442749      PMCID： PMC1855361          DOI： 10.1073/pnas.0610747104

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN： 0027-8424            Impact factor:   11.205


  14 in total

1.  Late-metal catalysts for ethylene homo- and copolymerization.

Authors:  S D Ittel; L K Johnson; M Brookhart
Journal:  Chem Rev       Date:  2000-04-12       Impact factor: 60.622

2.  A half-century of nonclassical organometallic chemistry: a personal perspective.

Authors:  F Albert Cotton
Journal:  Inorg Chem       Date:  2002-02-25       Impact factor: 5.165

3.  Isotope effects in C-H bond activation reactions by transition metals.

Authors:  William D Jones
Journal:  Acc Chem Res       Date:  2003-02       Impact factor: 22.384

4.  Agostic interactions in d0 metal alkyl complexes.

Authors:  Wolfgang Scherer; G Sean McGrady
Journal:  Angew Chem Int Ed Engl       Date:  2004-03-26       Impact factor: 15.336

5.  A rhenium-cyclohexane complex with preferential binding of axial C-H bonds: a probe into the relative ability of C-H, C-D, and C-C bonds as hyperconjugative electron donors?

Authors:  Douglas J Lawes; Tamim A Darwish; Timothy Clark; Jason B Harper; Graham E Ball
Journal:  Angew Chem Int Ed Engl       Date:  2006-07-03       Impact factor: 15.336

6.  Misassigned C-H...Cu agostic interaction in a copper(II) ephedrine derivative is actually a weak, multicentred hydrogen bond.

Authors:  Tejender S Thakur; Gautam R Desiraju
Journal:  Chem Commun (Camb)       Date:  2005-12-20       Impact factor: 6.222

7.  Palladium(II) beta-agostic alkyl cations and alkyl ethylene complexes: investigation of polymer chain isomerization mechanisms.

Authors:  L H Shultz; D J Tempel; M Brookhart
Journal:  J Am Chem Soc       Date:  2001-11-28       Impact factor: 15.419

8.  Insight into binding of alkanes to transition metals from NMR spectroscopy of isomeric pentane and isotopically labeled alkane complexes.

Authors:  Douglas J Lawes; Spili Geftakis; Graham E Ball
Journal:  J Am Chem Soc       Date:  2005-03-30       Impact factor: 15.419

9.  Mechanistic studies of nickel(II) alkyl agostic cations and alkyl ethylene complexes: investigations of chain propagation and isomerization in (alpha-diimine)Ni(II)-catalyzed ethylene polymerization.

Authors:  Mark D Leatherman; Steven A Svejda; Lynda K Johnson; Maurice Brookhart
Journal:  J Am Chem Soc       Date:  2003-03-12       Impact factor: 15.419

10.  Coordinative flexibility in hydrotris(methimazolyl)borate divalent metal compounds.

Authors:  Anil Cetin; Christopher J Ziegler
Journal:  Dalton Trans       Date:  2005-12-14       Impact factor: 4.390
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  70 in total

1.  Synthesis, characterization, and photophysical properties of three platinum(II) complexes bearing fluorescent analogues of the Di-2-pyridylmethane ligand.

Authors:  Justin J Wilson; Juliana Fedoce Lopes; Stephen J Lippard
Journal:  Inorg Chem       Date:  2010-06-07       Impact factor: 5.165

2.  Unsupported boron-carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation.

Authors:  Holger Braunschweig; Peter Brenner; Rian D Dewhurst; Ivo Krummenacher; Bernd Pfaffinger; Alfredo Vargas
Journal:  Nat Commun       Date:  2012-05-29       Impact factor: 14.919

3.  The coordination chemistry of saturated molecules.

Authors:  John E Bercaw; Jay A Labinger
Journal:  Proc Natl Acad Sci U S A       Date:  2007-04-24       Impact factor: 11.205

4.  Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds.

Authors:  Jun Pan; Mingjuan Su; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2011-08-02       Impact factor: 15.336

5.  Polar molecules catalyze CO insertion into metal-alkyl bonds through the displacement of an agostic C-H bond.

Authors:  Tian Zhou; Santanu Malakar; Steven L Webb; Karsten Krogh-Jespersen; Alan S Goldman
Journal:  Proc Natl Acad Sci U S A       Date:  2019-02-12       Impact factor: 11.205

6.  Identification and characterization of intramolecular γ-halo interaction in d0 complexes: a theoretical approach.

Authors:  Tanay Debnath; Tamalika Ash; Subhendu Sarkar; Abhijit K Das
Journal:  J Mol Model       Date:  2017-06-24       Impact factor: 1.810

7.  Structural snapshots of concerted double E-H bond activation at a transition metal centre.

Authors:  Joseph A B Abdalla; Alexa Caise; Christian P Sindlinger; Rémi Tirfoin; Amber L Thompson; Alison J Edwards; Simon Aldridge
Journal:  Nat Chem       Date:  2017-06-12       Impact factor: 24.427

8.  Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct.

Authors:  Noémie Lalaoui; Toby Woods; Thomas B Rauchfuss; Giuseppe Zampella
Journal:  Organometallics       Date:  2017-05-16       Impact factor: 3.876

9.  Thermochemistry and molecular structure of a remarkable agostic interaction in a heterobifunctional ruthenium-boron complex.

Authors:  Brian L Conley; Travis J Williams
Journal:  J Am Chem Soc       Date:  2010-02-17       Impact factor: 15.419

10.  Redox and structural properties of mixed-valence models for the active site of the [FeFe]-hydrogenase: progress and challenges.

Authors:  Aaron K Justice; Luca De Gioia; Mark J Nilges; Thomas B Rauchfuss; Scott R Wilson; Giuseppe Zampella
Journal:  Inorg Chem       Date:  2008-07-12       Impact factor: 5.165
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