Literature DB >> 16432580

Misassigned C-H...Cu agostic interaction in a copper(II) ephedrine derivative is actually a weak, multicentred hydrogen bond.

Tejender S Thakur1, Gautam R Desiraju.   

Abstract

Agostic interactions and weak hydrogen bonds to metal acceptors, M, are chemically and geometrically distinct, and this distinction must be maintained in the classification of new C-H...M interactions.

Entities:  

Year:  2005        PMID: 16432580     DOI: 10.1039/b514427b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  5 in total

1.  Agostic interactions in transition metal compounds.

Authors:  Maurice Brookhart; Malcolm L H Green; Gerard Parkin
Journal:  Proc Natl Acad Sci U S A       Date:  2007-04-18       Impact factor: 11.205

2.  Quantum chemical study of the mechanism of ethylene elimination in silylative coupling of olefins.

Authors:  Marcin Hoffmann; Bogdan Marciniec
Journal:  J Mol Model       Date:  2007-01-10       Impact factor: 1.810

3.  Facile C-H bond cleavage via a proton-coupled electron transfer involving a C-H...Cu(II) interaction.

Authors:  Xavi Ribas; Carlos Calle; Albert Poater; Alicia Casitas; Laura Gómez; Raül Xifra; Teodor Parella; Jordi Benet-Buchholz; Arthur Schweiger; George Mitrikas; Miquel Solà; Antoni Llobet; T Daniel P Stack
Journal:  J Am Chem Soc       Date:  2010-09-08       Impact factor: 15.419

4.  Supramolecular structures of NiII and CuII with the sterically demanding Schiff base dyes driven by cooperative action of preagostic and other non-covalent interactions.

Authors:  Alexey A Shiryaev; Tatyana M Burkhanova; Mariusz P Mitoraj; Mercedes Kukulka; Filip Sagan; Ghodrat Mahmoudi; Maria G Babashkina; Michael Bolte; Damir A Safin
Journal:  IUCrJ       Date:  2021-05-01       Impact factor: 4.769

5.  Evaluation of a chiral cubane-based Schiff base ligand in asymmetric catalysis reactions.

Authors:  Kyle F Biegasiewicz; Michelle L Ingalsbe; Jeffrey D St Denis; James L Gleason; Junming Ho; Michelle L Coote; G Paul Savage; Ronny Priefer
Journal:  Beilstein J Org Chem       Date:  2012-10-22       Impact factor: 2.883

  5 in total

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