| Literature DB >> 17402788 |
Marie Georgy1, Philippe Lesot, Jean-Marc Campagne.
Abstract
The preparation of the C4-C24 fragment of the macrolactin A is described. The adopted synthetic strategy involves two isomerizations to selectively construct the (8E,10Z) and (16E,18E) dienes, using a sequential Claisen rearrangement/allene isomerization and a Ph3P-catalyzed isomerization of an yne-one, respectively.Entities:
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Year: 2007 PMID： 17402788 DOI： 10.1021/jo0701942
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354