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Literature DB >> 17385917

Rhodium-catalyzed intramolecular C-H insertion of alpha-aryl-alpha-diazo ketones.

Abstract

Direct diazo transfer proceeds smoothly with alpha-aryl ketones. The derived alpha-aryl-alpha-diazo ketones cyclize efficiently with Rh catalysis to give the corresponding alpha-aryl cyclopentanones.

Entities: Chemical

Mesh：

Substances：
Ketones
Carbon
Hydrogen

Year: 2007 PMID： 17385917 PMCID： PMC3248813 DOI： 10.1021/jo0624694

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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