Literature DB >> 17347720

Isolating fluorinated carbocations.

Christos Douvris1, Evgenii S Stoyanov, Fook S Tham, Christopher A Reed.   

Abstract

Using carboranes as counterions, fluorinated benzyl-type carbocations such as (p-FC(6)H(4))(2)CF(+), (p-FC(6)H(4))(CH(3))CF(+) and fluorinated trityl ions are readily isolated for X-ray and IR structural characterization.

Entities:  

Year:  2007        PMID： 17347720     DOI： 10.1039/b617606b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Authors:  Christopher A Reed
Journal:  Acc Chem Res       Date:  2010-01-19       Impact factor: 22.384

Review 2.  Repurposing of F-gases: challenges and opportunities in fluorine chemistry.

Authors:  Daniel J Sheldon; Mark R Crimmin
Journal:  Chem Soc Rev       Date:  2022-06-20       Impact factor: 60.615

3.  Isolable fluorinated triphenylmethyl cation salts of [HCB11Cl11]-: demonstration of remarkable hydride affinity.

Authors:  S Olivia Gunther; Chun-I Lee; Ellen Song; Nattamai Bhuvanesh; Oleg V Ozerov
Journal:  Chem Sci       Date:  2022-04-04       Impact factor: 9.969

4.  Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.

Authors:  Vincent Lavallo; Guido D Frey; Shazia Kousar; Bruno Donnadieu; Guy Bertrand
Journal:  Proc Natl Acad Sci U S A       Date:  2007-08-13       Impact factor: 11.205

5.  Reactive p-block cations stabilized by weakly coordinating anions.

Authors:  Tobias A Engesser; Martin R Lichtenthaler; Mario Schleep; Ingo Krossing
Journal:  Chem Soc Rev       Date:  2015-11-27       Impact factor: 54.564

6.  The Influence of Halogenated Hypercarbon on Crystal Packing in the Series of 1-Ph-2-X-1,2-dicarba-closo-dodecaboranes (X = F, Cl, Br, I).

Authors:  Miroslav Havránek; Maksim A Samsonov; Josef Holub; Zdeňka Růžičková; Ladislav Drož; Aleš Růžička; Jindřich Fanfrlík; Drahomír Hnyk
Journal:  Molecules       Date:  2020-03-06       Impact factor: 4.411
  6 in total

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