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Literature DB >> 17283798

Rh(II)-catalysed room temperature aziridination of homoallyl-carbamates.

Christopher J Hayes¹, Peter W Beavis, Lesley A Humphries.

Abstract

Rhodium(II) catalysts and PhIO in benzene convert homoallylic carbamates into the corresponding aziridines at room temperature.

Entities: Chemical Gene

Mesh：

Substances：

Year: 2006 PMID： 17283798 DOI： 10.1039/b611662k

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

8 in total

1. 1,4-Diazaspiro[2.2]pentanes as a flexible platform for the synthesis of diamine-bearing stereotriads.

Authors: Jared W Rigoli; Luke A Boralsky; John C Hershberger; Dagmara Marston; Alan R Meis; Ilia A Guzei; Jennifer M Schomaker
Journal: J Org Chem Date: 2012-02-14 Impact factor: 4.354

2. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.

Authors: Minsoo Ju; Cale D Weatherly; Ilia A Guzei; Jennifer M Schomaker
Journal: Angew Chem Int Ed Engl Date: 2017-07-12 Impact factor: 15.336

3. Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer.

Authors: Minxue Huang; Tzuhsiung Yang; Jonathan D Paretsky; John F Berry; Jennifer M Schomaker
Journal: J Am Chem Soc Date: 2017-11-20 Impact factor: 15.419

4. Glycal Metallanitrenes for 2-Amino Sugar Synthesis: Amidoglycosylation of Gulal-, Allal-, Glucal-, and Galactal 3-Carbamates.

Authors: Simran Buttar; Julia Caine; Evelyne Goné; Reneé Harris; Jennifer Gillman; Roxanne Atienza; Ritu Gupta; Kimberly M Sogi; Lauren Jain; Nadia C Abascal; Yetta Levine; Lindsay M Repka; Christian M Rojas
Journal: J Org Chem Date: 2018-07-06 Impact factor: 4.354

Rh(II)-catalysed room temperature aziridination of homoallyl-carbamates.

1. 1,4-Diazaspiro[2.2]pentanes as a flexible platform for the synthesis of diamine-bearing stereotriads.

2. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations.

3. Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer.

4. Glycal Metallanitrenes for 2-Amino Sugar Synthesis: Amidoglycosylation of Gulal-, Allal-, Glucal-, and Galactal 3-Carbamates.

5. Allene functionalization via bicyclic methylene aziridines.

6. Chemoselective allene aziridination via Ag(I) catalysis.

7. Protecting group and solvent control of stereo- and chemoselectivity in glucal 3-carbamate amidoglycosylation.

8. Tunable, chemoselective amination via silver catalysis.