| Literature DB >> 17266158 |
Chunyang Jia1, Shi-Xia Liu, Christian Tanner, Claudia Leiggener, Antonia Neels, Lionel Sanguinet, Eric Levillain, Samuel Leutwyler, Andreas Hauser, Silvio Decurtins.
Abstract
To study the electronic interactions in donor-acceptor (D-A) ensembles, D and A fragments are coupled in a single molecule. Specifically, a tetrathiafulvalene (TTF)-fused dipyrido[3,2-a:2',3'-c]phenazine (dppz) compound having inherent redox centers has been synthesized and structurally characterized. Its electronic absorption, fluorescence emission, photoinduced intramolecular charge transfer, and electrochemical behavior have been investigated. The observed electronic properties are explained on the basis of density functional theory.Entities:
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Year: 2007 PMID: 17266158 DOI: 10.1002/chem.200601561
Source DB: PubMed Journal: Chemistry ISSN: 0947-6539 Impact factor: 5.236