Literature DB >> 17125379

A fluctuation theory analysis of the salting-out effect.

Robert M Mazo1.   

Abstract

An analysis of the salting-out, or Sechenow, effect is given in terms of Kirkwood-Buff, or fluctuation, integrals. The analysis is formally exact but cannot easily be applied in its original form. When the solute that is being salted out is sparingly soluble, simplifications arise and the theory can be used to compute one of the Kirkwood-Buff integrals which is otherwise difficult to obtain.

Year:  2006        PMID： 17125379     DOI： 10.1021/jp0656936

Source DB:  PubMed          Journal:  J Phys Chem B        ISSN： 1520-5207            Impact factor:   2.991


  5 in total

1.  Local Fluctuations in Solution: Theory and Applications.

Authors:  Elizabeth A Ploetz; Paul E Smith
Journal:  Adv Chem Phys       Date:  2013       Impact factor: 1.000

Review 2.  Recent applications of Kirkwood-Buff theory to biological systems.

Authors:  Veronica Pierce; Myungshim Kang; Mahalaxmi Aburi; Samantha Weerasinghe; Paul E Smith
Journal:  Cell Biochem Biophys       Date:  2007-11-28       Impact factor: 2.194

3.  Kirkwood-Buff theory of four and higher component mixtures.

Authors:  Myungshim Kang; Paul E Smith
Journal:  J Chem Phys       Date:  2008-06-28       Impact factor: 3.488

4.  On the theory of solute solubility in mixed solvents.

Authors:  Paul E Smith; Robert M Mazo
Journal:  J Phys Chem B       Date:  2008-06-05       Impact factor: 2.991

5.  Local fluctuations in solution mixtures.

Authors:  Elizabeth A Ploetz; Paul E Smith
Journal:  J Chem Phys       Date:  2011-07-28       Impact factor: 3.488
  5 in total

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