| Literature DB >> 17048871 |
Aurelio Mateo-Alonso1, Giulia Fioravanti, Massimo Marcaccio, Francesco Paolucci, Dhiredj C Jagesar, Albert M Brouwer, Maurizio Prato.
Abstract
The preparation and characterization of a solvent-switchable rotaxane that shuttles in the opposite direction to that expected are reported. The reverse shuttling is confirmed by NMR spectroscopy and can be monitored by cyclic voltammetry. The electrochemically generated anions on the fullerene moiety are stabilized by the closer proximity of the macrocycle.Entities:
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Year: 2006 PMID： 17048871 DOI： 10.1021/ol062277v
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005