| Literature DB >> 17048844 |
Adam R Yeager1, Geanna K Min, John A Porco, Scott E Schaus.
Abstract
Aryl ether C-glycoside scaffolds have been prepared from tri-O-acetyl-D-glucal by C-glycosylation followed by allylic substitution with phenols mediated by Pd(0). The aryl ethers were subjected to either [3,3]-sigmatropic rearrangement to produce 3-pyranyl-phenols or Au(III)-mediated ring contraction to create highly substituted tetrahydrofurans. [structure: see text]Entities:
Mesh：
Substances：
Year: 2006 PMID： 17048844 DOI： 10.1021/ol0618252
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005