Literature DB >> 17028732

Chiral polymers by iterative tandem catalysis.

Jeroen van Buijtenen1, Bart A C van As, Jan Meuldijk, Anja R A Palmans, Jef A J M Vekemans, L A Hulshof, E W Meijer.   

Abstract

Racemic omega-substituted caprolactones can be completely converted into chiral polyesters of remarkable MW and high ee by combining lipase-catalyzed ring-opening polymerization with Ru-catalyzed racemization.

Entities:  

Year:  2006        PMID: 17028732     DOI: 10.1039/b606241e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  (S)-6-Methyl-∊-caprolactone.

Authors:  Maxime A Siegler; Huub Kooijman; Anthony L Spek
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-02-20

Review 2.  Lipase-catalyzed polyester synthesis--a green polymer chemistry.

Authors:  Shiro Kobayashi
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2010       Impact factor: 3.493

  2 in total

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