| Literature DB >> 17014831 |
Pavel Cheshev1, Alberto Marra, Alessandro Dondoni.
Abstract
A multi-gram epoxidation of 3,4,6-tri-O-benzyl-D-glucal and D-galactal with dimethyldioxirane (DMDO) generated in situ from Oxone/acetone in a biphasic system (CH(2)Cl(2)-aqueous NaHCO(3)) resulted in the formation of the corresponding 1,2-anhydrosugars in a 99% yield and 100% selectivity. In a similar way, 3,4,6-tri-O-acetyl-D-glucal afforded a 7:1 mixture of the corresponding gluco and manno derivatives in an 87% overall yield.Entities:
Mesh：
Substances：
Year: 2006 PMID： 17014831 DOI： 10.1016/j.carres.2006.09.003
Source DB: PubMed Journal: Carbohydr Res ISSN： 0008-6215 Impact factor: 2.104