Literature DB >> 16984164

Synthesis and biradicaloid character of doubly linked corrole dimers.

Satoru Hiroto1, Ko Furukawa, Hiroshi Shinokubo, Atsuhiro Osuka.   

Abstract

Directly linked corrole dimer 1, which has a planar cyclooctatetraene in its core, has been synthesized from 2-borylcorrole in excellent yield. 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) oxidation of 1 provides its oxidized form 4, which has two NH protons in each corrole core. Dicorrole 4 and its Zn(II) complex 6 exhibit broad electronic absorption spectra, and magnetic measurement has revealed their biradicaloid character.

Entities:  

Year:  2006        PMID： 16984164     DOI： 10.1021/ja062654z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

Review 1.  Glycosylated Porphyrins, Phthalocyanines, and Other Porphyrinoids for Diagnostics and Therapeutics.

Authors:  Sunaina Singh; Amit Aggarwal; N V S Dinesh K Bhupathiraju; Gianluca Arianna; Kirran Tiwari; Charles Michael Drain
Journal:  Chem Rev       Date:  2015-08-28       Impact factor: 60.622

2.  Can Corrole Dimers Be Good Photosensitizers to Kill Bacteria?

Authors:  Paula S S Lacerda; Maria Bartolomeu; Ana T P C Gomes; Ana S Duarte; Adelaide Almeida; Maria A F Faustino; Maria G P M S Neves; Joana F B Barata
Journal:  Microorganisms       Date:  2022-06-07

3.  Highly planar diarylamine-fused porphyrins and their remarkably stable radical cations.

Authors:  Norihito Fukui; Wonhee Cha; Daiki Shimizu; Juwon Oh; Ko Furukawa; Hideki Yorimitsu; Dongho Kim; Atsuhiro Osuka
Journal:  Chem Sci       Date:  2016-08-01       Impact factor: 9.825

Review 4.  Porphyrinoids as a platform of stable radicals.

Authors:  Daiki Shimizu; Atsuhiro Osuka
Journal:  Chem Sci       Date:  2018-01-08       Impact factor: 9.825

5.  Phenalenyl-fused porphyrins with different ground states.

Authors:  Wangdong Zeng; Sangsu Lee; Minjung Son; Masatoshi Ishida; Ko Furukawa; Pan Hu; Zhe Sun; Dongho Kim; Jishan Wu
Journal:  Chem Sci       Date:  2015-02-04       Impact factor: 9.825

6.  Synthesis, Characterization, and the N Atom Transfer Reactivity of a Nitridochromium(V) Complex Stabilized by a Corrolato Ligand.

Authors:  Tanmoy Pain; Sruti Mondal; Subhrakant Jena; Dwaipayan Dutta Gupta; Himansu S Biswal; Sanjib Kar
Journal:  ACS Omega       Date:  2022-08-03

Review 7.  Metal Complexes of Singly, Doubly and Triply Linked Porphyrins and Corroles: An Insight into the Physicochemical Properties.

Authors:  Arijit Singha Hazari; Shubhadeep Chandra; Sanjib Kar; Biprajit Sarkar
Journal:  Chemistry       Date:  2022-03-07       Impact factor: 5.020

8.  Regioselective thiocyanation of corroles and the synthesis of gold nanoparticle-corrole assemblies.

Authors:  Kasturi Sahu; Sruti Mondal; Bratati Patra; Tanmoy Pain; Sajal Kumar Patra; Carsten Dosche; Sanjib Kar
Journal:  Nanoscale Adv       Date:  2019-11-21

Review 9.  Transition metal catalyzed borylation of functional π-systems.

Authors:  Hiroshi Shinokubo
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2014       Impact factor: 3.493
  9 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.