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Literature DB >> 16881629

Hydration and dynamic behavior of poly(N-isopropylacrylamide)s in aqueous solution: a sharp phase transition at the lower critical solution temperature.

Abstract

The number of hydrated water molecules per poly(N-isopropylacrylamide) monomer unit in homogeneous aqueous solution was determined to be 11 exactly and anew below the lower critical solution temperature of 32 degrees C employing high-frequency dielectric relaxation techniques.

Entities: Chemical

Year: 2006 PMID： 16881629 DOI： 10.1021/ja063990i

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

16 in total

1. Stimuli-Responsive Templated Polymer as a Target Receptor for a Conformation-based Electrochemical Sensing Platform.

Authors: Habib M N Ahmad; Gaurab Dutta; John Csoros; Bo Si; Rongfang Yang; Jeffrey M Halpern; W Rudolf Seitz; Edward Song
Journal: ACS Appl Polym Mater Date: 2020-12-09

2. Thermally responsive injectable hydrogel incorporating methacrylate-polylactide for hydrolytic lability.

Authors: Zuwei Ma; Devin M Nelson; Yi Hong; William R Wagner
Journal: Biomacromolecules Date: 2010-07-12 Impact factor: 6.988

3. UV resonance Raman determination of molecular mechanism of poly(N-isopropylacrylamide) volume phase transition.

Authors: Zeeshan Ahmed; Edward A Gooding; Konstantin V Pimenov; Luling Wang; Sanford A Asher
Journal: J Phys Chem B Date: 2009-04-02 Impact factor: 2.991

4. Thermosensitive multilayer hydrogels of poly(N-vinylcaprolactam) as nanothin films and shaped capsules.

Authors: Xing Liang; Veronika Kozlovskaya; Yi Chen; Oleksandra Zavgorodnya; Eugenia Kharlampieva
Journal: Chem Mater Date: 2012-09-13 Impact factor: 9.811

5. The Role of Backbone Hydration of Poly(N-isopropyl acrylamide) Across the Volume Phase Transition Compared to its Monomer.

Authors: Moritz H Futscher; Martine Philipp; Peter Müller-Buschbaum; Alfons Schulte
Journal: Sci Rep Date: 2017-12-05 Impact factor: 4.379

Hydration and dynamic behavior of poly(N-isopropylacrylamide)s in aqueous solution: a sharp phase transition at the lower critical solution temperature.

1. Stimuli-Responsive Templated Polymer as a Target Receptor for a Conformation-based Electrochemical Sensing Platform.

2. Thermally responsive injectable hydrogel incorporating methacrylate-polylactide for hydrolytic lability.

3. UV resonance Raman determination of molecular mechanism of poly(N-isopropylacrylamide) volume phase transition.

4. Thermosensitive multilayer hydrogels of poly(N-vinylcaprolactam) as nanothin films and shaped capsules.

5. The Role of Backbone Hydration of Poly(N-isopropyl acrylamide) Across the Volume Phase Transition Compared to its Monomer.

6. Evidence of a low-temperature dynamical transition in concentrated microgels.

7. Hybrid nanodiamond quantum sensors enabled by volume phase transitions of hydrogels.

8. Water-Polymer Coupling Induces a Dynamical Transition in Microgels.

9. On the molecular origin of the cooperative coil-to-globule transition of poly(N-isopropylacrylamide) in water.

10. Thermosensitive Hydration of Four Acrylamide-Based Polymers in Coil and Globule Conformations.