| Literature DB >> 16756273 |
Charlotte K A Gregson1, Vernon C Gibson, Nicholas J Long, Edward L Marshall, Phillip J Oxford, Andrew J P White.
Abstract
The activity of a single-site titanium-based lactide polymerization initiator supported by a ferrocenyl-derivatized salen ligand is shown to be modulated by a chemical redox switch; a substantially higher rate of propagation is found for the neutral catalyst compared to its oxidized dicationic ferrocenium counterpart.Entities:
Year: 2006 PMID： 16756273 DOI： 10.1021/ja061398n
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419