| Literature DB >> 16729140 |
Harry Adams1, Simon Jones, Isaac Ojea-Jimenez.
Abstract
Diels-Alder cycloadditions of p-benzoquinone with 9R-(1-methoxyethyl)anthracene provides a 60:40 ratio of cycloadducts when heated at reflux in xylene. Mechanistic studies to explore the origins of this selectivity have shown that at lower temperatures the kinetic product predominates, giving a 96:4 ratio of cycloadducts.Entities:
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Year: 2006 PMID： 16729140 DOI： 10.1039/b603819k
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876