Literature DB >> 16706523

Iron-catalyzed imination of sulfoxides and sulfides.

Olga García Mancheño1, Carsten Bolm.   

Abstract

[reaction: see text] The Fe(III)-catalyzed imination of sulfoxides and sulfides with sulfonylamides in the presence of iodinanes has been investigated. The best results were obtained when Fe(acac)(3) was used as a catalyst in combination with iodosylbenzene, providing an effective alternative (stereospecific) access to sulfoximines and sulfilimines.

Entities:  

Year:  2006        PMID： 16706523     DOI： 10.1021/ol060640s

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

Review 1.  Chemistry of polyvalent iodine.

Authors:  Viktor V Zhdankin; Peter J Stang
Journal:  Chem Rev       Date:  2008-12       Impact factor: 60.622

2.  Enantioselective imidation of sulfides via enzyme-catalyzed intermolecular nitrogen-atom transfer.

Authors:  Christopher C Farwell; John A McIntosh; Todd K Hyster; Z Jane Wang; Frances H Arnold
Journal:  J Am Chem Soc       Date:  2014-06-05       Impact factor: 15.419

3.  Redox-Neutral Organometallic Elementary Steps at Bismuth: Catalytic Synthesis of Aryl Sulfonyl Fluorides.

Authors:  Marc Magre; Josep Cornella
Journal:  J Am Chem Soc       Date:  2021-12-16       Impact factor: 15.419

4.  Accessing Perfluoroaryl Sulfonimidamides and Sulfoximines via Photogenerated Perfluoroaryl Nitrenes: Synthesis and Application as a Chiral Auxiliary.

Authors:  Giampiero Proietti; Julius Kuzmin; Azamat Z Temerdashev; Peter Dinér
Journal:  J Org Chem       Date:  2021-11-12       Impact factor: 4.354

5.  The use of chiral lithium amides in the desymmetrisation of N-trialkylsilyl dimethyl sulfoximines.

Authors:  Matthew J McGrath; Carsten Bolm
Journal:  Beilstein J Org Chem       Date:  2007-10-16       Impact factor: 2.883

6.  Transfer of Electrophilic NH Using Convenient Sources of Ammonia: Direct Synthesis of NH Sulfoximines from Sulfoxides.

Authors:  Marina Zenzola; Robert Doran; Leonardo Degennaro; Renzo Luisi; James A Bull
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-29       Impact factor: 15.336
  6 in total

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