Literature DB >> 16676938

Decarboxylation of 2,2'-bipyridinyl-4,4'-dicarboxylic acid diethyl ester during microwave synthesis of the corresponding trichelated ruthenium complex.

Thomas J Anderson1, Jill R Scott, Frank Millett, Bill Durham.   

Abstract

Microwave reaction of RuCl3 with 2,2'-bipyridinyl-4,4'-dicarboxylic acid diethyl ester (debpy) in ethylene glycol generated Ru(bpy)3(2+) instead of the expected Ru(debpy)3(2+). Gas chromatography-mass spectrometry analysis of the headspace revealed CO2, and Ru(bpy)3(2+) was recovered from the filtrate. Further experiments suggest that RuCl3 decarboxylates debpy during microwave synthesis.

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Year:  2006        PMID： 16676938      PMCID： PMC2542503          DOI： 10.1021/ic060008v

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  8 in total

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Authors:  Yu Liu; Yun Song; Yong Chen; Xue-Qing Li; Fei Ding; Rui-Qin Zhong
Journal:  Chemistry       Date:  2004-08-06       Impact factor: 5.236

2.  Synthesis, structure, and properties of [Pt(II)(diimine)(dithiolate)] dyes with 3,3'-, 4,4'-, and 5,5'-disubstituted bipyridyl: applications in dye-sensitized solar cells.

Authors:  Elaine A M Geary; Lesley J Yellowlees; Lorna A Jack; Iain D H Oswald; Simon Parsons; Narukuni Hirata; James R Durrant; Neil Robertson
Journal:  Inorg Chem       Date:  2005-01-24       Impact factor: 5.165

3.  Switching the redox mechanism: models for proton-coupled electron transfer from tyrosine and tryptophan.

Authors:  Martin Sjödin; Stenbjörn Styring; Henriette Wolpher; Yunhua Xu; Licheng Sun; Leif Hammarström
Journal:  J Am Chem Soc       Date:  2005-03-23       Impact factor: 15.419

4.  Synthesis and luminescent properties of novel lanthanide(III) beta-diketone complexes with nitrogen p,p'-disubstituted aromatic ligands.

Authors:  Anna Bellusci; Giovanna Barberio; Alessandra Crispini; Mauro Ghedini; Massimo La Deda; Daniela Pucci
Journal:  Inorg Chem       Date:  2005-03-21       Impact factor: 5.165

5.  Stereoselective recognition of tripeptides guided by encoded library screening: construction of chiral macrocyclic tetraamide ruthenium receptor for peptide sensing.

Authors:  Kuei-Hua Chang; Jen-Hai Liao; Chao-Tsen Chen; Barun K Mehta; Pi-Tai Chou; Jim-Min Fang
Journal:  J Org Chem       Date:  2005-03-18       Impact factor: 4.354

6.  Preparations and characterizations of bichromophoric systems composed of a ruthenium polypyridine complex connected to a difluoroborazaindacene or a zinc phthalocyanine chromophore.

Authors:  Fabrice Odobel; Hervé Zabri
Journal:  Inorg Chem       Date:  2005-08-08       Impact factor: 5.165

7.  Luminescent ruthenium(II) bipyridine-calix[4]arene complexes as receptors for lanthanide cations.

Authors:  Paul D Beer; Fridrich Szemes; Paolo Passaniti; Mauro Maestri
Journal:  Inorg Chem       Date:  2004-06-28       Impact factor: 5.165

8.  Amphiphilic ruthenium sensitizers and their applications in dye-sensitized solar cells.

Authors:  C Klein; Md K Nazeeruddin; D Di Censo; P Liska; Michael Grätzel
Journal:  Inorg Chem       Date:  2004-07-12       Impact factor: 5.165
  8 in total
  1 in total

1.  Synthesis and biological assessment of a ruthenium(II) cyclopentadienyl complex in breast cancer cells and on the development of zebrafish embryos.

Authors:  Golara Golbaghi; Irène Pitard; Matthieu Lucas; Mohammad Mehdi Haghdoost; Yossef López de Los Santos; Nicolas Doucet; Shunmoogum A Patten; J Thomas Sanderson; Annie Castonguay
Journal:  Eur J Med Chem       Date:  2020-01-03       Impact factor: 6.514
  1 in total

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