Literature DB >> 16551081

Cavitands with revolving doors regulate binding selectivities and rates in water.

Richard J Hooley1, Hillary J Van Anda, Julius Rebek.   

Abstract

A water-soluble self-folding cavitand has been prepared, featuring four benzoate groups attached to the open end. These benzoates act as rapidly "revolving doors" to the cavity. The cavitand shows increased selectivity for small hydrophobic guests and slower rates of guest exchange.

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Year:  2006        PMID: 16551081     DOI: 10.1021/ja058727g

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  8 in total

1.  Molecular recognition of organic ammonium ions in solution using synthetic receptors.

Authors:  Andreas Späth; Burkhard König
Journal:  Beilstein J Org Chem       Date:  2010-04-06       Impact factor: 2.883

2.  Metal-coordinated water-soluble cavitands act as C-H oxidation catalysts.

Authors:  Katherine E Djernes; Orly Moshe; Magi Mettry; Donald D Richards; Richard J Hooley
Journal:  Org Lett       Date:  2012-01-24       Impact factor: 6.005

Review 3.  Challenges and breakthroughs in recent research on self-assembly.

Authors:  Katsuhiko Ariga; Jonathan P Hill; Michael V Lee; Ajayan Vinu; Richard Charvet; Somobrata Acharya
Journal:  Sci Technol Adv Mater       Date:  2008-03-13       Impact factor: 8.090

4.  Preparative scale and convenient synthesis of a water-soluble, deep cavitand.

Authors:  Simone Mosca; Yang Yu; Julius Rebek
Journal:  Nat Protoc       Date:  2016-07-07       Impact factor: 13.491

5.  Electronic and steric effects in binding of deep cavitands.

Authors:  Richard J Hooley; Siddhartha R Shenoy; Julius Rebek
Journal:  Org Lett       Date:  2008-12-04       Impact factor: 6.005

6.  Ferrocene derivatives included in a water-soluble cavitand: are they electroinactive?

Authors:  Dagmara Podkoscielny; Richard J Hooley; Julius Rebek; Angel E Kaifer
Journal:  Org Lett       Date:  2008-06-07       Impact factor: 6.005

7.  Recognition of guests by water-stabilized cavitand hosts.

Authors:  Agustí Lledó; Richard J Hooley; Julius Rebek
Journal:  Org Lett       Date:  2008-07-26       Impact factor: 6.005

8.  On the mechanism of action of gated molecular baskets: The synchronicity of the revolving motion of gates and in/out trafficking of guests.

Authors:  Keith Hermann; Stephen Rieth; Hashem A Taha; Bao-Yu Wang; Christopher M Hadad; Jovica D Badjić
Journal:  Beilstein J Org Chem       Date:  2012-01-16       Impact factor: 2.883

  8 in total

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