Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Ferrocene derivatives included in a water-soluble cavitand: are they electroinactive?

Literature DB >> 18537255

Ferrocene derivatives included in a water-soluble cavitand: are they electroinactive?

Dagmara Podkoscielny¹, Richard J Hooley, Julius Rebek, Angel E Kaifer.

Abstract

The formation in aqueous solution of kinetically stable inclusion complexes between a deep-cavity cavitand and several redox active ferrocene derivatives was demonstrated using (1)H NMR spectroscopy. The electrochemical kinetics of the inclusion complexes was strongly attenuated as compared to that observed with the free guests.

Entities: Chemical

Mesh：

Substances：

Year: 2008 PMID： 18537255 PMCID： PMC2654615 DOI： 10.1021/ol8010375

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

14 in total

1. Kinetically stable complexes in water: the role of hydration and hydrophobicity.

Authors: Shannon M Biros; Elke C Ullrich; Fraser Hof; Laurent Trembleau; Julius Rebek
Journal: J Am Chem Soc Date: 2004-03-10 Impact factor: 15.419

2. Complexation of ferrocene derivatives by the cucurbit[7]uril host: a comparative study of the cucurbituril and cyclodextrin host families.

Authors: Woo Sung Jeon; Kwangyul Moon; Sang Hyun Park; Hyungpil Chun; Young Ho Ko; Jin Yong Lee; Eun Sung Lee; S Samal; N Selvapalam; Mikhail V Rekharsky; Vladimir Sindelar; David Sobransingh; Yoshihisa Inoue; Angel E Kaifer; Kimoon Kim
Journal: J Am Chem Soc Date: 2005-09-21 Impact factor: 15.419

3. A deep, water-soluble cavitand acts as a phase-transfer catalyst for hydrophobic species.

Authors: Richard J Hooley; Shannon M Biros; Julius Rebek
Journal: Angew Chem Int Ed Engl Date: 2006-05-19 Impact factor: 15.336

4. Normal hydrocarbons tumble rapidly in a deep, water-soluble cavitand.

Authors: Richard J Hooley; Shannon M Biros; Julius Rebek
Journal: Chem Commun (Camb) Date: 2005-12-14 Impact factor: 6.222

5. Noncovalent encapsulation of cobaltocenium inside resorcinarene molecular capsules.

Authors: Ivy Philip; Angel E Kaifer
Journal: J Org Chem Date: 2005-03-04 Impact factor: 4.354

6. New dendrimers containing a single cobaltocenium unit covalently attached to the apical position of Newkome dendrons: electrochemistry and guest binding interactions with cucurbit[7]uril.

Authors: David Sobransingh; Angel E Kaifer
Journal: Langmuir Date: 2006-12-05 Impact factor: 3.882

7. Encapsulation of ferrocene and peripheral electrostatic attachment of viologens to dimeric molecular capsules formed by an octaacid, deep-cavity cavitand.

Authors: Dagmara Podkoscielny; Ivy Philip; Corinne L D Gibb; Bruce C Gibb; Angel E Kaifer
Journal: Chemistry Date: 2008 Impact factor: 5.236

Ferrocene derivatives included in a water-soluble cavitand: are they electroinactive?

1. Kinetically stable complexes in water: the role of hydration and hydrophobicity.

2. Complexation of ferrocene derivatives by the cucurbit[7]uril host: a comparative study of the cucurbituril and cyclodextrin host families.

3. A deep, water-soluble cavitand acts as a phase-transfer catalyst for hydrophobic species.

4. Normal hydrocarbons tumble rapidly in a deep, water-soluble cavitand.

5. Noncovalent encapsulation of cobaltocenium inside resorcinarene molecular capsules.

6. New dendrimers containing a single cobaltocenium unit covalently attached to the apical position of Newkome dendrons: electrochemistry and guest binding interactions with cucurbit[7]uril.

7. Encapsulation of ferrocene and peripheral electrostatic attachment of viologens to dimeric molecular capsules formed by an octaacid, deep-cavity cavitand.

8. Extraction of hydrophobic species into a water-soluble synthetic receptor.

9. Molecular inclusion of organometallic sandwich complexes within hybrid cavitand-resorcin[4]arene receptors.

10. Electrochemically driven formation of a molecular capsule around the ferrocenium ion.

1. Site-specific installation and study of electroactive units in every layer of dendrons.