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Literature DB >> 16504568

Mononuclear copper active-oxygen complexes.

Abstract

There have been significant advances in the understanding of the dioxygen-activation chemistry of mononuclear copper monooxygenases such as peptidylglycine alpha-amidating monooxygenase and dopamine beta-monooxygenase (DbetaM). Recent structural and spectroscopic studies on a series of biomimetic model compounds have provided new and valuable insights into the key reactive intermediates involved in the dioxygen processing at the mononuclear copper reaction centers in biological systems.

Entities: Chemical

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Year: 2006 PMID： 16504568 DOI： 10.1016/j.cbpa.2006.02.012

Source DB: PubMed Journal: Curr Opin Chem Biol ISSN： 1367-5931 Impact factor: 8.822

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Cited

50 in total

1. An anionic, tetragonal copper(II) superoxide complex.

Authors: Patrick J Donoghue; Aalo K Gupta; David W Boyce; Christopher J Cramer; William B Tolman
Journal: J Am Chem Soc Date: 2010-10-26 Impact factor: 15.419

2. Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes.

Authors: Shunichi Fukuzumi; Laleh Tahsini; Yong-Min Lee; Kei Ohkubo; Wonwoo Nam; Kenneth D Karlin
Journal: J Am Chem Soc Date: 2012-04-12 Impact factor: 15.419

3. CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism.

Authors: Heather R Lucas; Gerald J Meyer; Kenneth D Karlin
Journal: J Am Chem Soc Date: 2010-09-22 Impact factor: 15.419

4. Perturbing the Copper(III)-Hydroxide Unit through Ligand Structural Variation.

Authors: Debanjan Dhar; Gereon M Yee; Andrew D Spaeth; David W Boyce; Hongtu Zhang; Büsra Dereli; Christopher J Cramer; William B Tolman
Journal: J Am Chem Soc Date: 2015-12-22 Impact factor: 15.419

5. Rapid C-H bond activation by a monocopper(III)-hydroxide complex.

Authors: Patrick J Donoghue; Jacqui Tehranchi; Christopher J Cramer; Ritimukta Sarangi; Edward I Solomon; William B Tolman
Journal: J Am Chem Soc Date: 2011-10-17 Impact factor: 15.419

6. Effects of electron-deficient beta-diketiminate and formazan supporting ligands on copper(I)-mediated dioxygen activation.

Authors: Sungjun Hong; Lyndal M R Hill; Aalo K Gupta; Benjamin D Naab; Joe B Gilroy; Robin G Hicks; Christopher J Cramer; William B Tolman
Journal: Inorg Chem Date: 2009-05-18 Impact factor: 5.165

Mononuclear copper active-oxygen complexes.

1. An anionic, tetragonal copper(II) superoxide complex.

2. Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes.

3. CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism.

4. Perturbing the Copper(III)-Hydroxide Unit through Ligand Structural Variation.

5. Rapid C-H bond activation by a monocopper(III)-hydroxide complex.

6. Effects of electron-deficient beta-diketiminate and formazan supporting ligands on copper(I)-mediated dioxygen activation.

7. Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex.

Review 8. Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO).

9. Isolation of a 2-hydroxytetrahydrofuran complex from copper-promoted hydroxylation of THF.

10. Formally Copper(III)-Alkylperoxo Complexes as Models of Possible Intermediates in Monooxygenase Enzymes.