Literature DB >> 23886308

Isolation of a 2-hydroxytetrahydrofuran complex from copper-promoted hydroxylation of THF.

Mohammad Reza Halvagar1, William B Tolman.   

Abstract

A complex of a binucleating macrocyclic ligand comprising a [Cu(II)(μ-OH)Na](2+) core reacts with CuI in THF/CH3CN to yield a novel species with a deprotonated 2-hydroxytetrahydrofuran (THF-2-ol) bridging between Cu(II) and Na(I) ions. The complexes were characterized by X-ray crystallography, electron paramagnetic resonance spectroscopy, and electrospray ionization mass spectrometry. (18)O-labeling studies support incorporation of the O atom from μ-OH into the coordinated THF-2-ol ligand.

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Year:  2013        PMID： 23886308      PMCID： PMC3799914          DOI： 10.1021/ic401446s

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  21 in total

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