Literature DB >> 16502506

Study on the reactions of azo compounds with acyl halides mediated by Sm/TiCl4.

Xue Li1, Yong-min Zhang.   

Abstract

Amides can be obtained in good to excellent yield by Sm/TiCl(4) mediated reductive cleavage of N=N bond in azo compounds and successive acylation in one pot. It offers an alternative method for the synthesis of amides from very simple starting materials directly.

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Year:  2006        PMID： 16502506      PMCID： PMC1419058          DOI： 10.1631/jzus.2006.B0198

Source DB:  PubMed          Journal:  J Zhejiang Univ Sci B        ISSN： 1673-1581            Impact factor:   3.066


  4 in total

1.  Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI(2), the Kagan Reagent.

Authors:  A Krief; A M Laval
Journal:  Chem Rev       Date:  1999-03-10       Impact factor: 60.622

2.  Sequencing Reactions with Samarium(II) Iodide.

Authors:  Gary A. Molander; Christina R. Harris
Journal:  Chem Rev       Date:  1996-02-01       Impact factor: 60.622

3.  Reductive cyclodimerization of arylmethylidenemalononitriles promoted by samarium and catalytic amount of iodine: facile synthesis of cyclopentene derivatives.

Authors:  Jue Chen; Yong-min Zhang
Journal:  J Zhejiang Univ Sci       Date:  2004-02

4.  A novel reduction of diketones with i-RMgBr catalyzed by Cp2TiCl2 and deoxygenation of sulfoxides by Cp2TiCl2/Al system.

Authors:  Yong-min Zhang; Mao-qin Lin; Yong-ping Yu
Journal:  J Zhejiang Univ Sci       Date:  2004-10
  4 in total

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