| Literature DB >> 15362186 |
Yong-min Zhang1, Mao-qin Lin, Yong-ping Yu.
Abstract
Alpha-diketones and beta-diketones react with Grignard reagents in the presence of a catalytic amount of Cp2TiCl2 to yield alpha-ketols and corresponding ketones respectively. Sulfoxides can be deoxygenated by Cp2TiCl2/Al system. The possible mechanisms are also discussed.Entities:
Mesh：
Substances：
Year: 2004 PMID： 15362186 PMCID： PMC1388720 DOI： 10.1631/jzus.2004.1175
Source DB: PubMed Journal: J Zhejiang Univ Sci ISSN： 1009-3095