Literature DB >> 16432569

Iron hydrogenase active site mimic holding a proton and a hydride.

Lennart Schwartz1, Gerriet Eilers, Lars Eriksson, Adolf Gogoll, Reiner Lomoth, Sascha Ott.   

Abstract

The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the title species was characterized by IR and NMR spectroscopy and is reduced at more positive potential than any other mimic of this kind.

Mesh：

Substances：

Year:  2005        PMID： 16432569     DOI： 10.1039/b514280f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  10 in total

1.  Unsaturated, mixed-valence diiron dithiolate model for the H(ox) state of the [FeFe] hydrogenase.

Authors:  Aaron K Justice; Thomas B Rauchfuss; Scott R Wilson
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

2.  Isomerization of the hydride complexes [HFe2(SR)2(PR3)(x)(CO)(6-x)]+ (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenases.

Authors:  Bryan E Barton; Giuseppe Zampella; Aaron K Justice; Luca De Gioia; Thomas B Rauchfuss; Scott R Wilson
Journal:  Dalton Trans       Date:  2009-09-16       Impact factor: 4.390

3.  Favorable Protonation of the (μ-edt)[Fe(2)(PMe(3))(4)(CO)(2)(H-terminal)](+) Hydrogenase Model Complex Over Its Bridging μ-H Counterpart: A Spectroscopic and DFT Study.

Authors:  Mary Grace I Galinato; C Matthew Whaley; Dean Roberts; Peng Wang; Nicolai Lehnert
Journal:  Eur J Inorg Chem       Date:  2011-03       Impact factor: 2.524

4.  Vibrational analysis of the model complex (mu-edt)[Fe(CO)(3)](2) and comparison to iron-only hydrogenase: the activation scale of hydrogenase model systems.

Authors:  Mary Grace I Galinato; C Matthew Whaley; Nicolai Lehnert
Journal:  Inorg Chem       Date:  2010-04-05       Impact factor: 5.165

5.  Studies on the Condensation Pathway to and Properties of Diiron Azadithiolate Carbonyls.

Authors:  Jane L Stanley; Thomas B Rauchfuss; Scott R Wilson
Journal:  Organometallics       Date:  2007       Impact factor: 3.876

6.  Synthetic models for the active site of the [FeFe]-hydrogenase: catalytic proton reduction and the structure of the doubly protonated intermediate.

Authors:  Maria E Carroll; Bryan E Barton; Thomas B Rauchfuss; Patrick J Carroll
Journal:  J Am Chem Soc       Date:  2012-11-05       Impact factor: 15.419

7.  Nature of hydrogen interactions with Ni(II) complexes containing cyclic phosphine ligands with pendant nitrogen bases.

Authors:  Aaron D Wilson; R K Shoemaker; A Miedaner; J T Muckerman; Daniel L DuBois; M Rakowski DuBois
Journal:  Proc Natl Acad Sci U S A       Date:  2007-03-08       Impact factor: 11.205

8.  Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.

Authors:  Jane L Stanley; Zachariah M Heiden; Thomas B Rauchfuss; Scott R Wilson; Luca De Gioia; Guiseppe Zampella
Journal:  Organometallics       Date:  2008-01       Impact factor: 3.876

9.  [FeFe] Hydrogenase active site model chemistry in a UiO-66 metal-organic framework.

Authors:  Sonja Pullen; Souvik Roy; Sascha Ott
Journal:  Chem Commun (Camb)       Date:  2017-05-04       Impact factor: 6.222

10.  Computational investigation of [FeFe]-hydrogenase models: characterization of singly and doubly protonated intermediates and mechanistic insights.

Authors:  Mioy T Huynh; Wenguang Wang; Thomas B Rauchfuss; Sharon Hammes-Schiffer
Journal:  Inorg Chem       Date:  2014-09-10       Impact factor: 5.165
  10 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.