| Literature DB >> 16358294 |
Patrycja Seroka1, Marcin Płosiński, Jacek Czub, Paweł Sowiński, Jan Pawlak.
Abstract
D-Glucose, D-mannose and L-rhamnose were reacted with a racemic mixture of 2-butanol, and the resulting alpha-glycosides were analyzed by 1H NMR with COSY and NOESY experiments. Conformational analysis of alpha-glycosidic bonds performed with molecular modeling and appropriate heteronuclear long-range coupling measurements and combined with analysis of dipolar couplings observed in NOESY spectra allowed the assignment of absolute configuration in the aglycones of elucidated alpha-glycosides. Copyright 2005 John Wiley & Sons, Ltd.Entities:
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Year: 2006 PMID： 16358294 DOI： 10.1002/mrc.1735
Source DB: PubMed Journal: Magn Reson Chem ISSN： 0749-1581 Impact factor: 2.447