Literature DB >> 16351088

Chemoenzymatic dynamic kinetic resolution of primary amines.

Jens Paetzold1, Jan E Bäckvall.   

Abstract

An efficient process for dynamic kinetic resolution of amines was developed by combining a ruthenium-catalyzed racemization with a lipase-catalyzed resolution. A variety of unfunctionalized primary amines were transformed into one enantiomer of the amide in high yield and high enantioselectivity.

Entities:  

Mesh：

Substances：

Year:  2005        PMID： 16351088     DOI： 10.1021/ja056306t

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  Biocatalysis: Chiral cascades.

Authors:  Jian-bo Wang; Manfred T Reetz
Journal:  Nat Chem       Date:  2015-12       Impact factor: 24.427

2.  Single-operation deracemization of 3H-indolines and tetrahydroquinolines enabled by phase separation.

Authors:  Aaron D Lackner; Andrew V Samant; F Dean Toste
Journal:  J Am Chem Soc       Date:  2013-09-11       Impact factor: 15.419

3.  Kinetic Resolution of Benzylamines via Palladium(II)-Catalyzed C-H Cross-Coupling.

Authors:  Kai-Jiong Xiao; Ling Chu; Gang Chen; Jin-Quan Yu
Journal:  J Am Chem Soc       Date:  2016-06-10       Impact factor: 15.419

4.  Dynamic Covalent Kinetic Resolution.

Authors:  Yan Zhang; Yang Zhang; Olof Ramström
Journal:  Catal Rev Sci Eng       Date:  2019-09-11       Impact factor: 20.217

5.  Room-temperature enantioselective C-H iodination via kinetic resolution.

Authors:  Ling Chu; Kai-Jiong Xiao; Jin-Quan Yu
Journal:  Science       Date:  2014-10-24       Impact factor: 47.728

6.  Development of dynamic kinetic resolution on large scale for (±)-1-phenylethylamine.

Authors:  Lisa K Thalén; Jan-E Bäckvall
Journal:  Beilstein J Org Chem       Date:  2010-09-13       Impact factor: 2.883

7.  Asymmetric synthesis of nonracemic primary amines via spiroborate-catalyzed reduction of pure (E)- and (Z)-O-benzyloximes: applications toward the synthesis of calcimimetic agents.

Authors:  Wenhua Ou; Sandraliz Espinosa; Héctor J Meléndez; Silvia M Farré; Jaime L Alvarez; Valerie Torres; Ileanne Martínez; Kiara M Santiago; Margarita Ortiz-Marciales
Journal:  J Org Chem       Date:  2013-05-13       Impact factor: 4.354

8.  A Practical Electrophilic Nitrogen Source for the Synthesis of Chiral Primary Amines by Copper-Catalyzed Hydroamination.

Authors:  Sheng Guo; Jeffrey C Yang; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2018-11-08       Impact factor: 15.419

Review 9.  Chemoenzymatic dynamic kinetic resolution: a powerful tool for the preparation of enantiomerically pure alcohols and amines.

Authors:  Oscar Verho; Jan-E Bäckvall
Journal:  J Am Chem Soc       Date:  2015-03-19       Impact factor: 15.419

10.  Co-immobilization of an enzyme and a metal into the compartments of mesoporous silica for cooperative tandem catalysis: an artificial metalloenzyme.

Authors:  Karin Engström; Eric V Johnston; Oscar Verho; Karl P J Gustafson; Mozaffar Shakeri; Cheuk-Wai Tai; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-12       Impact factor: 15.336
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.