| Literature DB >> 16305204 |
Hae-Jo Kim1, Hyunwoo Kim, Gamil Alhakimi, Eui June Jeong, Nirusha Thavarajah, Lisa Studnicki, Alicja Koprianiuk, Alan J Lough, Junghun Suh, Jik Chin.
Abstract
Crystal structure and activation entropy data indicate that H-bond directed diaza-Cope rearrangement of chiral diimines takes place with a high degree of preorganization. CD spectroscopy and HPLC data show that there is inversion of stereochemistry for the reaction with excellent enantioselectivity.Entities:
Year: 2005 PMID： 16305204 DOI： 10.1021/ja055776k
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419