Literature DB >> 16288520

A new method for translating the asymmetric Ni/Cr-mediated coupling reactions from stoichiometric to catalytic.

Kosuke Namba1, Sheng Cui, Jiashi Wang, Yoshito Kishi.   

Abstract

[reaction: see text] A new method has been developed for effectively translating the degree of asymmetric induction and the chemical yield achieved in the stoichiometric asymmetric Ni/Cr-mediated coupling to a catalytic asymmetric process via a chiral sulfonamide ligand. It has also been shown that the Ni catalyst plays a central role. Among a number of the Ni catalysts, the 2,9-dimethylphenanthroline/NiCl(2) complex (7) has been found to be the most effective.

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Year:  2005        PMID: 16288520     DOI: 10.1021/ol052084s

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  5 in total

Review 1.  The chemistry and biology of mycolactones.

Authors:  Matthias Gehringer; Karl-Heinz Altmann
Journal:  Beilstein J Org Chem       Date:  2017-08-11       Impact factor: 2.883

2.  6-(1H-Indol-3-yl)-4-phenyl-2,2'-bi-pyridine-5-carbonitrile.

Authors:  Weijun Zhu; Yan Xiang; Songlei Zhu
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-05-07

3.  Dramatic improvement in catalyst loadings and molar ratios of coupling partners for Ni/Cr-mediated coupling reactions: heterobimetallic catalysts.

Authors:  Xiang Liu; James A Henderson; Takeo Sasaki; Yoshito Kishi
Journal:  J Am Chem Soc       Date:  2009-11-25       Impact factor: 15.419

4.  Electrochemical Nozaki-Hiyama-Kishi Coupling: Scope, Applications, and Mechanism.

Authors:  Yang Gao; David E Hill; Wei Hao; Brendon J McNicholas; Julien C Vantourout; Ryan G Hadt; Sarah E Reisman; Donna G Blackmond; Phil S Baran
Journal:  J Am Chem Soc       Date:  2021-06-15       Impact factor: 16.383

5.  Chromium(II)-catalyzed enantioselective arylation of ketones.

Authors:  Gang Wang; Shutao Sun; Ying Mao; Zhiyu Xie; Lei Liu
Journal:  Beilstein J Org Chem       Date:  2016-12-19       Impact factor: 2.883

  5 in total

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