Literature DB >> 16261245

Synthesis of phosphorus esters by transesterification mediated by N-heterocyclic carbenes (NHCs).

Rohit Singh1, Steven P Nolan.   

Abstract

The versatile nucleophilic organic catalysts N-heterocyclic carbenes (NHCs) have been shown to effectively mediate the transesterification of phosphorus esters under mild conditions; user-friendly imidazolium salts can also be employed as pre-catalysts.

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Year:  2005        PMID： 16261245     DOI： 10.1039/b509783e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Carbene catalysts.

Authors:  Jennifer L Moore; Tomislav Rovis
Journal:  Top Curr Chem       Date:  2010

2.  Full kinetics investigation of the formation reaction of phosphonate esters in the gas-phase: a theoretical study.

Authors:  Mohammad Amin Kazemian; Sayyed Mostafa Habibi-Khorassani; Malek Taher Maghsoodlu; Ali Ebrahimi
Journal:  J Mol Model       Date:  2014-03-16       Impact factor: 1.810

3.  Mechanistic insights into the insertion and addition reactions of group 13 analogues of the six-membered N-heterocyclic carbenes: interplay of electrophilicity, basicity, and aromaticity governing the reactivity.

Authors:  Zheng-Feng Zhang; Ming-Der Su
Journal:  RSC Adv       Date:  2021-06-04       Impact factor: 4.036

4.  3,3'-Dibenzyl-1,1'-(2,4,6-trimethyl-m-phenyl-enedimethyl-ene)diimidazol-3-ium dibromide.

Authors:  Rosenani A Haque; Abbas Washeel Salman; Paremala Nadarajan; Madhukar Hemamalini; Hoong-Kun Fun
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-02-16
  4 in total

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