Literature DB >> 16231899

Positional control of encapsulated atoms inside a fullerene cage by exohedral addition.

Michio Yamada1, Tsukasa Nakahodo, Takatsugu Wakahara, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Masahiro Kako, Kenji Yoza, Ernst Horn, Naomi Mizorogi, Kaoru Kobayashi, Shigeru Nagase.   

Abstract

The exohedrally functionalized derivative of endohedral metallofullerene, Ce2@C80(Mes2SiCH2SiMes2), was successfully synthesized and fully characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that the free random motion of two metal atoms in Ce2@C80 is controlled inside the cage by exohedral chemical functionalization.

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Year:  2005        PMID： 16231899     DOI： 10.1021/ja054346r

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  A layered ionic crystal of polar Li@C(60) superatoms.

Authors:  Shinobu Aoyagi; Eiji Nishibori; Hiroshi Sawa; Kunihisa Sugimoto; Masaki Takata; Yasumitsu Miyata; Ryo Kitaura; Hisanori Shinohara; Hiroshi Okada; Takeshi Sakai; Yoshihiro Ono; Kazuhiko Kawachi; Kuniyoshi Yokoo; Shoichi Ono; Kenji Omote; Yasuhiko Kasama; Shinsuke Ishikawa; Takashi Komuro; Hiromi Tobita
Journal:  Nat Chem       Date:  2010-06-20       Impact factor: 24.427

2.  The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes.

Authors:  Matthew Gregson; Erli Lu; David P Mills; Floriana Tuna; Eric J L McInnes; Christoph Hennig; Andreas C Scheinost; Jonathan McMaster; William Lewis; Alexander J Blake; Andrew Kerridge; Stephen T Liddle
Journal:  Nat Commun       Date:  2017-02-03       Impact factor: 14.919

Review 3.  Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds.

Authors:  Masahiro Kako; Shigeru Nagase; Takeshi Akasaka
Journal:  Molecules       Date:  2017-07-14       Impact factor: 4.411

4.  Redox-active metal-metal bonds between lanthanides in dimetallofullerenes.

Authors:  Alexey A Popov
Journal:  Curr Opin Electrochem       Date:  2017-12-18

5.  A diuranium carbide cluster stabilized inside a C80 fullerene cage.

Authors:  Xingxing Zhang; Wanlu Li; Lai Feng; Xin Chen; Andreas Hansen; Stefan Grimme; Skye Fortier; Dumitru-Claudiu Sergentu; Thomas J Duignan; Jochen Autschbach; Shuao Wang; Yaofeng Wang; Giorgios Velkos; Alexey A Popov; Nabi Aghdassi; Steffen Duhm; Xiaohong Li; Jun Li; Luis Echegoyen; W H Eugen Schwarz; Ning Chen
Journal:  Nat Commun       Date:  2018-07-16       Impact factor: 14.919

6.  Synthesis and characterization of carbene derivatives of Th@C 3v(8)-C82 and U@C 2v(9)-C82: exceptional chemical properties induced by strong actinide-carbon cage interaction.

Authors:  Xinye Liu; Bo Li; Wei Yang; Yang-Rong Yao; Le Yang; Jiaxin Zhuang; Xiaomeng Li; Peng Jin; Ning Chen
Journal:  Chem Sci       Date:  2020-12-21       Impact factor: 9.825
  6 in total

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