| Literature DB >> 16209502 |
Yumiko Kawai1, Hiromune Ando, Hideya Ozeki, Mamoru Koketsu, Hideharu Ishihara.
Abstract
[reaction: see text] The reaction between alpha-glycosyl bromides and potassium p-methylselenobenzoate yields beta-p-methylbenzoyl selenoglycosides. The acyl selenoglycosides were activated by the action of a secondary amine and Cs2CO3 to produce an anomeric selenolate anion, which reacted in situ with various electrophiles to yield novel selenoglycosides while retaining the anomeric stereochemistry.Entities:
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Year: 2005 PMID： 16209502 DOI： 10.1021/ol051804s
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005