Literature DB >> 16205813

Triazene formation via reaction of imidazol-2-ylidenes with azides.

Dimitri M Khramov1, Christopher W Bielawski.   

Abstract

Treatment of N-heterocyclic carbenes (as their free carbenes or generated in situ) with alkyl, aryl, acyl or tosyl azides afforded the respective substituted triazenes in excellent yields.

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Year:  2005        PMID： 16205813     DOI： 10.1039/b508679e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Direct Intracellular Delivery of Benzene Diazonium Ions As Observed by Increased Tyrosine Phosphorylation.

Authors:  Natasha R Cornejo; Bismark Amofah; Austin Lipinski; Paul R Langlais; Indraneel Ghosh; John C Jewett
Journal:  Biochemistry       Date:  2022-03-18       Impact factor: 3.321

2.  Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodi-phospho-rane iridium inter-mediate: substitution of one phosphine moiety of a carbodi-phospho-rane by an organic azide.

Authors:  Gabriel Julian Partl; Felix Nussbaumer; Walter Schuh; Holger Kopacka; Klaus Wurst; Paul Peringer
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2019-01-01

3.  Me CAAC=N- : A Cyclic (Alkyl)(Amino)Carbene Imino Ligand.

Authors:  James T Goettel; Haopeng Gao; Simon Dotzauer; Holger Braunschweig
Journal:  Chemistry       Date:  2020-01-09       Impact factor: 5.236

4.  Reactions of Mesityl Azide with Ferrocene-Based N-Heterocyclic Germylenes, Stannylenes and Plumbylenes, Including PPh2 -Functionalised Congeners.

Authors:  Robin Guthardt; Lisa Oetzel; Tobias Lang; Clemens Bruhn; Ulrich Siemeling
Journal:  Chemistry       Date:  2022-06-08       Impact factor: 5.020

5.  Crystal structure of (E)-1,3-dimethyl-2-[3-(3-nitro-phen-yl)triaz-2-en-1-yl-idene]-2,3-di-hydro-1H-imidazole.

Authors:  Siddappa Patil; Alejandro Bugarin
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-09-20

6.  New Insights in Frustrated Lewis Pair Chemistry with Azides.

Authors:  Devin H A Boom; Andrew R Jupp; Martin Nieger; Andreas W Ehlers; J Chris Slootweg
Journal:  Chemistry       Date:  2019-09-09       Impact factor: 5.236
  6 in total

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