Literature DB >> 16190695

Macroscopic expression of the chirality of amino alcohols by a double amplification mechanism in liquid crystalline media.

Rienk Eelkema1, Ben L Feringa.   

Abstract

The central chirality of simple amino alcohols was amplified by binding to a dynamically axially chiral biphenol receptor and expressed as supramolecular chirality by effecting a change from a nematic to a cholesteric liquid crystalline phase.

Entities:  

Year:  2005        PMID： 16190695     DOI： 10.1021/ja054352n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Knotting a molecular strand can invert macroscopic effects of chirality.

Authors:  Nathalie Katsonis; Federico Lancia; David A Leigh; Lucian Pirvu; Alexander Ryabchun; Fredrik Schaufelberger
Journal:  Nat Chem       Date:  2020-08-03       Impact factor: 24.427

2.  The interplay of configuration and conformation in helical perylenequinones: Insights from chirality induction in liquid crystals and calculations.

Authors:  Elisa Frezza; Silvia Pieraccini; Stefania Mazzini; Alberta Ferrarini; Gian Piero Spada
Journal:  Beilstein J Org Chem       Date:  2012-01-24       Impact factor: 2.883

3.  Determination of the absolute stereostructure of a cyclic azobenzene from the crystal structure of the precursor containing a heavy element.

Authors:  Reji Thomas; Nobuyuki Tamaoki
Journal:  Beilstein J Org Chem       Date:  2016-10-19       Impact factor: 2.883

4.  Chiral amplification in a cyanobiphenyl nematic liquid crystal doped with helicene-like derivatives.

Authors:  Alberta Ferrarini; Silvia Pieraccini; Stefano Masiero; Gian Piero Spada
Journal:  Beilstein J Org Chem       Date:  2009-10-07       Impact factor: 2.883

5.  Absolute Configuration Assignment to Chiral Natural Products by Biphenyl Chiroptical Probes: The Case of the Phytotoxins Colletochlorin A and Agropyrenol.

Authors:  Ernesto Santoro; Stefania Vergura; Patrizia Scafato; Sandra Belviso; Marco Masi; Antonio Evidente; Stefano Superchi
Journal:  J Nat Prod       Date:  2020-02-24       Impact factor: 4.050
  5 in total

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