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Literature DB >> 16172673

Ru-based oxidation catalysis.

Mario Pagliaro¹, Sandro Campestrini, Rosaria Ciriminna.

Abstract

Ranging from the oxidative conversion of water to O(2) to the elegant hydroxylation of olefins and to oxidative dehydrogenation of alcohols Ru-mediated oxidations are finding increasing application due to the unique properties of this extremely versatile transition metal, whose oxidation state can vary from -II to +VIII. Covering recent developments in both homogeneously and heterogeneously catalysed oxidations (in liquid-phase as well as in novel reaction media), this tutorial review aims to provide investigators with a general picture of the chemical and structural origins of the excellent performance of many ruthenium catalysts and to promote further advancement that, it is envisaged, will soon benefit society at large.

Entities: Chemical Gene

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Year: 2005 PMID： 16172673 DOI： 10.1039/b507094p

Source DB: PubMed Journal: Chem Soc Rev ISSN： 0306-0012 Impact factor: 54.564

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Cited

8 in total

1. Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru^V-Oxo with Significant Oxyl Radical Character.

Authors: Jaruwan Amtawong; David Balcells; Jarett Wilcoxen; Rex C Handford; Naomi Biggins; Andy I Nguyen; R David Britt; T Don Tilley
Journal: J Am Chem Soc Date: 2019-12-05 Impact factor: 15.419

Ru-based oxidation catalysis.

1. Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru^V-Oxo with Significant Oxyl Radical Character.

Review 2. Homogeneity of Supported Single-Atom Active Sites Boosting the Selective Catalytic Transformations.

3. Crystal structure of (2,2'-bi-pyridine-κ²N,N')bis-(3,5-di-tert-butyl-o-benzo-quinonato-κ²O,O')ruthenium(II).

4. A novel one-pot synthesis of flavones.

Review 5. Quantum Dots Compete at the Acme of MXene Family for the Optimal Catalysis.

6. trans-Dibromidotetra-kis-(pyridine-κN)ruthenium(II).

7. Elucidating the mechanism of the Ley-Griffith (TPAP) alcohol oxidation.

Review 8. Efficient Aerobic Oxidation of Organic Molecules by Multistep Electron Transfer.

Ru-based oxidation catalysis.

1. Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal RuV-Oxo with Significant Oxyl Radical Character.

Review 2. Homogeneity of Supported Single-Atom Active Sites Boosting the Selective Catalytic Transformations.

3. Crystal structure of (2,2'-bi-pyridine-κ2N,N')bis-(3,5-di-tert-butyl-o-benzo-quinonato-κ2O,O')ruthenium(II).

4. A novel one-pot synthesis of flavones.

Review 5. Quantum Dots Compete at the Acme of MXene Family for the Optimal Catalysis.

6. trans-Dibromidotetra-kis-(pyridine-κN)ruthenium(II).

7. Elucidating the mechanism of the Ley-Griffith (TPAP) alcohol oxidation.

Review 8. Efficient Aerobic Oxidation of Organic Molecules by Multistep Electron Transfer.

1. Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru^V-Oxo with Significant Oxyl Radical Character.

3. Crystal structure of (2,2'-bi-pyridine-κ²N,N')bis-(3,5-di-tert-butyl-o-benzo-quinonato-κ²O,O')ruthenium(II).