Literature DB >> 16045310

Inversion of the rectifying effect in diblock molecular diodes by protonation.

Gustavo M Morales1, Ping Jiang, Shenwen Yuan, Youngu Lee, Arturo Sanchez, Wei You, Luping Yu.   

Abstract

A new molecular diode based on biphenyl-co-bispyrimidine was synthesized and showed a pronounced rectifying effect. Further studies indicate that protonation on the nitrogen atoms of the diode molecule by strong acids can reversibly alter the rectifying direction. This phenomenon can be envisioned as a starting point for single molecule detection devices.

Entities:  

Year:  2005        PMID: 16045310     DOI: 10.1021/ja051332c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  7 in total

1.  Rectification and stability of a single molecular diode with controlled orientation.

Authors:  Ismael Díez-Pérez; Joshua Hihath; Youngu Lee; Luping Yu; Lyudmyla Adamska; Mortko A Kozhushner; Ivan I Oleynik; Nongjian Tao
Journal:  Nat Chem       Date:  2009-10-11       Impact factor: 24.427

2.  Quantum Transport Through Tunable Molecular Diodes.

Authors:  Joshua Tobechukwu Obodo; Altynbek Murat; Udo Schwingenschlögl
Journal:  Sci Rep       Date:  2017-08-04       Impact factor: 4.379

3.  In-Place Modulation of Rectification in Tunneling Junctions Comprising Self-Assembled Monolayers.

Authors:  Yong Ai; Andrii Kovalchuk; Xinkai Qiu; Yanxi Zhang; Sumit Kumar; Xintai Wang; Martin Kühnel; Kasper Nørgaard; Ryan C Chiechi
Journal:  Nano Lett       Date:  2018-11-09       Impact factor: 11.189

4.  Rectifying properties of oligo(phenylene ethynylene) heterometallic molecular junctions: molecular length and side group effects.

Authors:  Xiao-Xiao Fu; Rui-Qin Zhang; Guang-Ping Zhang; Zong-Liang Li
Journal:  Sci Rep       Date:  2014-09-15       Impact factor: 4.379

5.  High electronic couplings of single mesitylene molecular junctions.

Authors:  Yuki Komoto; Shintaro Fujii; Tomoaki Nishino; Manabu Kiguchi
Journal:  Beilstein J Nanotechnol       Date:  2015-12-18       Impact factor: 3.649

6.  Transition voltages respond to synthetic reorientation of embedded dipoles in self-assembled monolayers.

Authors:  Andrii Kovalchuk; Tarek Abu-Husein; Davide Fracasso; David A Egger; Egbert Zojer; Michael Zharnikov; Andreas Terfort; Ryan C Chiechi
Journal:  Chem Sci       Date:  2015-10-22       Impact factor: 9.825

7.  Proton-triggered switch based on a molecular transistor with edge-on gate.

Authors:  Lianwei Li; Wai-Yip Lo; Zhengxu Cai; Na Zhang; Luping Yu
Journal:  Chem Sci       Date:  2016-01-26       Impact factor: 9.825

  7 in total

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