Literature DB >> 15877121

Structure and magnetic properties of a novel copper halide framework {[tBuNH3]2[Cu3(mu3-OH)(mu2-H2O)Cl7]}n synthesized via in situ templation.

Tristram Chivers1, Zhiyong Fu, Laurence K Thompson.   

Abstract

The use of the tris(alkylamido)phosphate OP[N(H)tBu]3 as an in situ source of the templating agent [tBuNH3]+ produces the copper halide chain {[tBuNH3]2[Cu3(mu3-OH)(mu2-H2O)Cl7]}n (1) in a solvothermal process; the novel antiferromagnetically coupled trinuclear fragment Cu3(OH)(H2O)Cl7 is the building block in the polymeric anion in .

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Year:  2005        PMID: 15877121     DOI: 10.1039/b501040c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Hexa-μ-chlorido-μ(4)-oxido-tetra-kis-({1-[(pyridin-2-yl)meth-yl]-1H-benzimidazole-κN}copper(II)).

Authors:  Hui Li; Hongshi Jiang; Hong Sun
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-09-14

2.  Hexa-μ2-chlorido-μ4-oxido-tetra-kis[(morpholine-κN)copper(II)] methanol disolvate.

Authors:  Kateryna Gubina; Vladimir Ovchynnikov; Vladimir Amirkhanov
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2014-06-21
  2 in total

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