Literature DB >> 15787520

Pd(OH)2/C-mediated selective oxidation of silyl enol ethers by tert-butylhydroperoxide, a useful method for the conversion of ketones to alpha,beta-enones or beta-silyloxy-alpha,beta-enones.

Jin-Quan Yu1, Hai-Chen Wu, E J Corey.   

Abstract

[reaction: see text] Pd(OH)2-catalyzed oxidation of silyl enol ethers by t-BuOOH gives either beta-silyloxy-alpha,beta-enones or alpha,beta-enones in good yields depending on the base used.

Entities:  

Year:  2005        PMID： 15787520     DOI： 10.1021/ol050284y

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  17 in total

1.  Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products.

Authors:  Andrei V Iosub; Shannon S Stahl
Journal:  ACS Catal       Date:  2016-10-24       Impact factor: 13.084

2.  Enantioselective synthesis of (-)-jiadifenin, a potent neurotrophic modulator.

Authors:  Lynnie Trzoss; Jing Xu; Michelle H Lacoske; William C Mobley; Emmanuel A Theodorakis
Journal:  Org Lett       Date:  2011-08-03       Impact factor: 6.005

3.  Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.

Authors:  Phong V Pham; David A Nagib; David W C MacMillan
Journal:  Angew Chem Int Ed Engl       Date:  2011-05-23       Impact factor: 15.336

Review 4.  If C-H bonds could talk: selective C-H bond oxidation.

Authors:  Timothy Newhouse; Phil S Baran
Journal:  Angew Chem Int Ed Engl       Date:  2011-03-16       Impact factor: 15.336

5.  Synthesis of cyclic enones via direct palladium-catalyzed aerobic dehydrogenation of ketones.

Authors:  Tianning Diao; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2011-08-29       Impact factor: 15.419

6.  Total Synthesis and Anticancer Activity of (+)-Hypercalin C and Congeners.

Authors:  Yongfeng Tao; Keighley Reisenauer; Joseph H Taube; Daniel Romo
Journal:  Angew Chem Int Ed Engl       Date:  2019-02-01       Impact factor: 15.336

7.  Allylic oxidations catalyzed by dirhodium caprolactamate via aqueous tert-butyl hydroperoxide: the role of the tert-butylperoxy radical.

Authors:  Emily C McLaughlin; Hojae Choi; Kan Wang; Grace Chiou; Michael P Doyle
Journal:  J Org Chem       Date:  2009-01-16       Impact factor: 4.354

8.  Illicium sesquiterpenes: divergent synthetic strategy and neurotrophic activity studies.

Authors:  Lynnie Trzoss; Jing Xu; Michelle H Lacoske; William C Mobley; Emmanuel A Theodorakis
Journal:  Chemistry       Date:  2013-03-22       Impact factor: 5.236

9.  Terminal olefins to linear α,β-unsaturated ketones: Pd(II)/hypervalent iodine co-catalyzed Wacker oxidation-dehydrogenation.

Authors:  Marinus A Bigi; M Christina White
Journal:  J Am Chem Soc       Date:  2013-05-17       Impact factor: 15.419

10.  Evolution of a Unified Strategy for Complex Sesterterpenoids: Progress toward Astellatol and the Total Synthesis of (-)-Nitidasin.

Authors:  Daniel T Hog; Florian M E Huber; Gonzalo Jiménez-Osés; Peter Mayer; Kendall N Houk; Dirk Trauner
Journal:  Chemistry       Date:  2015-08-20       Impact factor: 5.236
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