The transition of polymers into a network of polymers alters per se the water activity.

We have found that polyacrylamide gels cross-linked with bisacrylamide induce a larger macromolecular osmotic pressure than the non cross-linked gels. This means also that in the cross-linked gels hydration water is held more tightly to the polymer, i.e., more work is needed to remove water, than in the non cross-linked gel. Since the chemical nature of the two gels is extremely similar, we propose that the formation of the network alters per se the water activity.