Literature DB >> 15695915

Tris[4-(4-nitrophenyl)-3-aza-3-butenyl]amine: pi-stacked chains of hydrogen-bonded R(2)(2)26 dimers.

Christopher Glidewell1, John N Low, Janet M S Skakle, James L Wardell.   

Abstract

In the title compound {alternative name: N'-(4-nitrobenzylidene)-N,N-bis[2-(4-nitrobenzylideneamino)ethyl]-1,2-ethanediamine}, C27H27N7O6, the three independent NCH2CH2N=CHC6H4NO2 fragments all exhibit different conformations, resulting from the different direction-specific intra- and intermolecular interactions experienced. The molecules are linked by a single C-H...O hydrogen bond into centrosymmetric R(2)(2)(26) dimers, which are linked by pi-pi stacking interactions into [111] chains and, more weakly, into (01-1) sheets.

Entities:  

Year:  2005        PMID: 15695915     DOI: 10.1107/S0108270104033141

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Tris{2-[(2-amino-benzyl-idene)amino]-ethyl}amine.

Authors:  Mariana Elizondo García; Sylvain Bernès; Nancy Pérez Rodríguez; Perla Elizondo Martínez
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-11-06
  1 in total

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