| Literature DB >> 15584754 |
Jianzhang Zhao1, Matthew G Davidson, Mary F Mahon, Gabriele Kociok-Köhn, Tony D James.
Abstract
Chiral fluorescent boronic acid 1 was found to be a highly enantioselective, chemoselective, and sensitive sensor for sugar acids, such as tartaric acid. Enantioselectivities (K(R)/K(S)) of up to 550:1, chemoselectivity up to 11,000:1, and sensitivities in the micromolar range with sensor 1 were observed. Single-crystal X-ray analysis was used to confirm the structure of the fluorescent species.Entities:
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Year: 2004 PMID： 15584754 DOI： 10.1021/ja046289s
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419