| Literature DB >> 15446852 |
Miki Kassai1, R Gnana Ravi, Sarah J Shealy, Kathryn B Grant.
Abstract
4,13-Diaza-18-crown-6 substantially increases the rate of zirconium(IV) hydrolysis of unactivated peptide amide bonds under near-physiological conditions of temperature and pH. In the presence of this azacrown ether, ZrCl(4) efficiently hydrolyses both neutral and negatively charged peptides (pH 7.0-7.3, 37-60 degrees C).Entities:
Mesh:
Substances:
Year: 2004 PMID: 15446852 DOI: 10.1021/ic049433j
Source DB: PubMed Journal: Inorg Chem ISSN: 0020-1669 Impact factor: 5.165