Literature DB >> 15340627

Electrochemical reduction of an imidazolium cation: a convenient preparation of imidazol-2-ylidenes and their observation in an ionic liquid.

Brian Gorodetsky1, Taramatee Ramnial, Neil R Branda, Jason A C Clyburne.   

Abstract

1,3-Bis(2,4,6-trimethylphenyl)imidazolium chloride is reduced electrochemically and chemically to produce a nucleophilic carbene, namely 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene. The carbene was also shown to be compatible with and persistent in the ionic liquid tetradecyl(trihexyl)phosphonium chloride.

Entities:  

Year:  2004        PMID： 15340627     DOI： 10.1039/b407386j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Carbene-Stabilized Main Group Radicals and Radical Ions.

Authors:  Caleb D Martin; Michele Soleilhavoup; Guy Bertrand
Journal:  Chem Sci       Date:  2013-08-01       Impact factor: 9.825

Review 2.  NHC in Imidazolium Acetate Ionic Liquids: Actual or Potential Presence?

Authors:  Isabella Chiarotto; Leonardo Mattiello; Fabiana Pandolfi; Daniele Rocco; Marta Feroci
Journal:  Front Chem       Date:  2018-08-28       Impact factor: 5.221

3.  Predictive energetic tuning of C-Nucleophiles for the electrochemical capture of carbon dioxide.

Authors:  Haley A Petersen; Abdulaziz W Alherz; Taylor A Stinson; Chloe G Huntzinger; Charles B Musgrave; Oana R Luca
Journal:  iScience       Date:  2022-03-03

4.  Electrocarboxylation of 1-chloro-(4-isobutylphenyl)ethane with a silver cathode in ionic liquids: an environmentally benign and efficient way to synthesize Ibuprofen.

Authors:  Silvia Mena; Jessica Sanchez; Gonzalo Guirado
Journal:  RSC Adv       Date:  2019-05-14       Impact factor: 4.036

Review 5.  On the chemical stabilities of ionic liquids.

Authors:  Subbiah Sowmiah; Venkatesan Srinivasadesikan; Ming-Chung Tseng; Yen-Ho Chu
Journal:  Molecules       Date:  2009-09-25       Impact factor: 4.411

6.  In Situ Anodically Oxidized BMIm-BF4: A Safe and Recyclable BF3 Source.

Authors:  Martina Bortolami; Leonardo Mattiello; Vincenzo Scarano; Fabrizio Vetica; Marta Feroci
Journal:  J Org Chem       Date:  2021-07-02       Impact factor: 4.354
  6 in total

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