Literature DB >> 15327309

Preparation of stable alkyl complexes of Ni(I) and their one-electron oxidation to Ni(II) complex cations.

Kristina D Kitiachvili1, Daniel J Mindiola, Gregory L Hillhouse.   

Abstract

The three-coordinate nickel(I) alkyl complexes (dtbpe)Ni(CH2CMe3) (2), (dtbpe)Ni(CH2SiMe3) (3), and (dtbpe)Ni(CH2CMe2Ph) (4) have been prepared by treatment of [(dtbpe)NiCl]2 with alkyllithium reagents. While thermally robust, they each undergo mild one-electron oxidation to give the corresponding Ni(II) complex cations [(dtbpe)Ni(CH2CMe3)+] (5), [(dtbpe)Ni(CH2SiMe3)+] (6), and [(dtbpe)Ni(CH2CMe2Ph)+] (7) as red-brown [PF6-] or [BArF4-] salts. In contrast to cationic amido and phosphido analogues that undergo alpha-deprotonation to afford imido and phosphinidene derivatives, deprotonation of 5-7 occurs at a gamma-CH3 group to give metallacyclobutane products (dtbpe)Ni(CH2CMe2CH2) (8), (dtbpe)Ni(CH2SiMe2CH2) (9), and (dtbpe)Ni(CH2CPhMeCH2) (10), not (dtbpe)Ni=CHR.

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Year:  2004        PMID： 15327309     DOI： 10.1021/ja047052z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  Binuclear complexes containing a methylnickel moiety: relevance to organonickel intermediates in acetyl coenzyme A synthase catalysis.

Authors:  William G Dougherty; Krishnan Rangan; Molly J O'Hagan; Glenn P A Yap; Charles G Riordan
Journal:  J Am Chem Soc       Date:  2008-09-19       Impact factor: 15.419

2.  Arene C-H amination at nickel in terphenyl-diphosphine complexes with labile metal-arene interactions.

Authors:  David E Herbert; Nadia C Lara; Theodor Agapie
Journal:  Chemistry       Date:  2013-10-14       Impact factor: 5.236

3.  Reversible nickel-metallacycle formation with a phosphinimine-based pincer ligand.

Authors:  Xiujing Xing; Shaoguang Zhang; Laura M Thierer; Michael R Gau; Patrick J Carroll; Neil C Tomson
Journal:  Dalton Trans       Date:  2020-05-27       Impact factor: 4.390

4.  Synthesis and characterization of three-coordinate Ni(III)-imide complexes.

Authors:  Vlad M Iluc; Alexander J M Miller; John S Anderson; Marisa J Monreal; Mark P Mehn; Gregory L Hillhouse
Journal:  J Am Chem Soc       Date:  2011-07-28       Impact factor: 15.419

5.  Catalytic Reductive Carbene Transfer Reactions.

Authors:  Christopher Uyeda; Annah E Kalb
Journal:  Chem Catal       Date:  2022-02-04

6.  Nickel(I) Aryl Species: Synthesis, Properties, and Catalytic Activity.

Authors:  Megan Mohadjer Beromi; Gourab Banerjee; Gary W Brudvig; Nilay Hazari; Brandon Q Mercado
Journal:  ACS Catal       Date:  2018-02-13       Impact factor: 13.084

7.  [Ni(cod)2][Al(OR(F))4], a Source for Naked Nickel(I) Chemistry.

Authors:  Miriam M Schwab; Daniel Himmel; Sylwia Kacprzak; Daniel Kratzert; Valentin Radtke; Philippe Weis; Kallol Ray; Ernst-Wilhelm Scheidt; Wolfgang Scherer; Bas de Bruin; Stefan Weber; Ingo Krossing
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-13       Impact factor: 15.336

8.  Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex.

Authors:  Haolin Yin; Gregory C Fu
Journal:  J Am Chem Soc       Date:  2019-09-10       Impact factor: 15.419

9.  Insertion of CO2 Mediated by a (Xantphos)NiI -Alkyl Species.

Authors:  Justin B Diccianni; Chunhua T Hu; Tianning Diao
Journal:  Angew Chem Int Ed Engl       Date:  2019-08-14       Impact factor: 15.336

10.  Redox Activity of Pyridine-Oxazoline Ligands in the Stabilization of Low-Valent Organonickel Radical Complexes.

Authors:  Clifton L Wagner; Gabriel Herrera; Qiao Lin; Chunhua T Hu; Tianning Diao
Journal:  J Am Chem Soc       Date:  2021-04-01       Impact factor: 15.419
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