Literature DB >> 15264845

Oxidative cyclizations: the asymmetric synthesis of (-)-alliacol A.

John Mihelcic1, Kevin D Moeller.   

Abstract

A tandem anodic coupling-Friedel-Crafts alkylation strategy has been used to rapidly complete the asymmetric synthesis of alliacol A. The anodic oxidation reaction allowed for the generation of a new bond between two nucleophiles. In the synthesis, the absolute stereochemistry of the final natural product is set relative to a methyl group that is incorporated early in the sequence using an asymmetric Michael reaction.

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Year:  2004        PMID： 15264845     DOI： 10.1021/ja048085h

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  12 in total

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4.  Intramolecular anodic olefin coupling reactions and the synthesis of cyclic amines.

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