Literature DB >> 15237164

1-[(4-Chlorobenzoyl)methyl]-4-(N,N-dimethylamino)pyridinium bromide sesquihydrate and 1-[(4-bromobenzoyl)methyl]-4-(N,N-dimethylamino)pyridinium bromide sesquihydrate.

T V Sundar1, V Parthasarathi, K Sarkunam, M Nallu, B Walfort, H Lang.   

Abstract

The title compounds, C15H16ClN2O+.Br-.1.5H2O and C15H16BrN2O+.Br-.1.5H2O, are isomorphous. The benzene ring is oriented nearly normal to the pyridine ring in both compounds. The molecular packing is mainly influenced by intermolecular O-H...O and O-H...Br interactions, as well as weak intramolecular C-H...O interactions. The H2OBr- units form an extended water-bromide chain, with a bridging water molecule on a twofold axis.

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Year:  2004        PMID: 15237164     DOI: 10.1107/S0108270104010923

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  Dibromidobis(1-ethyl-2,6-dimethyl-pyridinium-4-olate-κO)zinc(II).

Authors:  M Thenmozhi; A Philominal; S Dhanuskodi; M N Ponnuswamy
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-12-18

2.  Synthesis, intermolecular interactions and biological activities of two new organic-inorganic hybrids C6H10N2,2Br and C6H10N2,2Cl·H2O.

Authors:  Intissar Hamdi; Intidhar Bkhairia; Andreas Roodt; Thierry Roisnel; Moncef Nasri; Houcine Naïli
Journal:  RSC Adv       Date:  2020-02-04       Impact factor: 4.036

  2 in total

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